Jw. Lee et al., HIGH ION DENSITY PLASMA-ETCHING OF INGAP, ALINP, AND ALGAP IN CH4 H-2/AR/, Journal of the Electrochemical Society, 143(3), 1996, pp. 1093-1098
High microwave power (1000 W) electron cyclotron resonance CH4/H-2/Ar
discharges produce etch rates for In0.5Ga0.5P, Al0.5In0.5P0.5, and Al0
.5Ga0.5P of similar to 2000 Angstrom min(-1) at moderate RF power leve
ls (150 W) and low pressure (1.5 mTorr). This is approximately a facto
r of five faster than for conventional reactive ion etching conditions
where much higher ion energies are necessary. The etched surfaces are
smooth over a wide range of CH4-to-H-2 ratios and microwave powers. A
lInP is more resistant to preferential loss of P from the near-surface
during etching than is InGaP. While the etching is ion-driven, pure A
r discharges produce rough surfaces and the CH4/H-2 is necessary in th
e achievement of acceptable morphologies.