BICONTINUOUS PHASE IN DIBLOCK COPOLYMER MELTS WITH ADDED HOMOPOLYMER

Authors
Citation
Hw. Xi et St. Milner, BICONTINUOUS PHASE IN DIBLOCK COPOLYMER MELTS WITH ADDED HOMOPOLYMER, Macromolecules, 29(7), 1996, pp. 2404-2411
Citations number
21
Categorie Soggetti
Polymer Sciences
Journal title
ISSN journal
00249297
Volume
29
Issue
7
Year of publication
1996
Pages
2404 - 2411
Database
ISI
SICI code
0024-9297(1996)29:7<2404:BPIDCM>2.0.ZU;2-B
Abstract
We compute in the strong-segregation regime the phase diagram of A-B d iblock copolymer with added B homopolymer to see if the bicontinuous p hase can be stabilized by adding homopolymers. Our work is motivated b y the results of Ajdari and Leibler, who showed using a bending expans ion that a single copolymer bilayer in excess homopolymer is unstable to Gaussian bends if the copolymers are sufficiently asymmetric. Our m ethods, which are not limited to a bending expansion, determine the re gion of homopolymer concentration and copolymer asymmetry for which a bicontinuous phase might be stable.