We investigate baryogenesis at a first-order electroweak phase transit
ion in the presence of a CP-violating condensate on the bubble walls,
in the regime in which the bubble walls are ''thick,'' in the sense th
at fermions interact with the plasma many times as the bubble wall pas
ses. Such a condensate is present in multi-Higgs-doublet extensions of
the standard model and may be formed via an instability in the minima
l standard model. We concentrate on particles with typical thermal ene
rgies in the plasma, whose interactions with the wall are accurately d
escribed by the WKB approximation, in which a classical chiral force i
s evident. The deviations from thermal equilibrium produced by the mot
ion of the wall are then treated using a classical Boltzmann equation
which we solve in a fluid approximation. From the resulting equations
we find two effects important for baryogenesis: (i) a classical chiral
force term due to the CP-violating background and (ii) a term arising
from hypercharge-violating interactions which are pushed out of equil
ibrium by the background field. Provided the wall propagates slower th
an the speed of sound, both terms lead to the diffusion of a chiral as
ymmetry in front of the wall. This can produce a baryon asymmetry of t
he observed magnitude for typical wall velocities and thicknesses.