NOVEL DOUBLE FUNCTIONAL-GROUP TRANSFORMATION - ONE-FLASK CONVERSION OF 1-NITROCYCLOALKENES TO TERMINALLY UNSATURATED NITRILES

Authors
TSO HH GILBERT BA HWU JR
Citation
Hh. Tso et al., NOVEL DOUBLE FUNCTIONAL-GROUP TRANSFORMATION - ONE-FLASK CONVERSION OF 1-NITROCYCLOALKENES TO TERMINALLY UNSATURATED NITRILES, Journal of the Chemical Society, Chemical Communications, (8), 1993, pp. 669-670
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
8
Year of publication
1993
Pages
669 - 670
Database
ISI
SICI code
0022-4936(1993):8<669:NDFT-O>2.0.ZU;2-W
Abstract
A new method has been developed for the conversion of 1-nitrocycloalke nes to terminally unsaturated nitriles in one flask by use of Me3SiCH2 MgCl (1.8 equiv.) and PCl3 (2.5 equiv.) in tetrahydrofuran.