OMEGA-MONO N-ALKYLATION OF LINEAR TETRAAMINES THROUGH THE REACTION OFALDEHYDES AND KETONES ON THEIR TRICARBONYL CHROMIUM, MOLYBDENUM OR TUNGSTEN COMPLEXES
Jj. Yaouanc et al., OMEGA-MONO N-ALKYLATION OF LINEAR TETRAAMINES THROUGH THE REACTION OFALDEHYDES AND KETONES ON THEIR TRICARBONYL CHROMIUM, MOLYBDENUM OR TUNGSTEN COMPLEXES, Journal of the Chemical Society, Chemical Communications, (8), 1993, pp. 696-698
The reductive amination of carbonyl compounds by the non-coordinated a
mino function of the fac-LM(CO)3 tridentate complexes of 1,4,7,10-tetr
aazadecane, 1,5,8,12-tetraazadodecane and 1,5,9,13-tetraazatridecane h
as been selectively achieved giving rise to omega-mono N-functionalize
d linear tetraamines.