A RATE-ACCELERATING NONCOVALENTLY ASSEMBLED SYSTEM FOR THIAZOLIUM-CATALYZED OXIDATIVE DECARBOXYLATION OF PYRUVATE IN CHLOROFORM ACETONITRILE

Authors
OHSHIMA S TAMURA N NABESHIMA T YANO Y
Citation
S. Ohshima et al., A RATE-ACCELERATING NONCOVALENTLY ASSEMBLED SYSTEM FOR THIAZOLIUM-CATALYZED OXIDATIVE DECARBOXYLATION OF PYRUVATE IN CHLOROFORM ACETONITRILE, Journal of the Chemical Society, Chemical Communications, (8), 1993, pp. 712-713
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
8
Year of publication
1993
Pages
712 - 713
Database
ISI
SICI code
0022-4936(1993):8<712:ARNASF>2.0.ZU;2-Y
Abstract
It is found that a thiazolium ion having a thymine moiety accelerates the rate of the oxidative decarboxylation of pyruvate in the presence of a 2,6-diamidopyridine derivative bearing a crown ether and Na+ in C HCl3-MeCN (9 : 1 v/v).