SYNTHESIS, STEREOCHEMISTRY, AND THERMOLYSIS OF BETA-AMINOALKYLBORANES

Authors
KAWASHIMA T YAMASHITA N OKAZAKI R
Citation
T. Kawashima et al., SYNTHESIS, STEREOCHEMISTRY, AND THERMOLYSIS OF BETA-AMINOALKYLBORANES, Chemistry Letters, (3), 1996, pp. 213-214
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
3
Year of publication
1996
Pages
213 - 214
Database
ISI
SICI code
0366-7022(1996):3<213:SSATOB>2.0.ZU;2-4
Abstract
erythro- and threo-beta-Amino boranes Mes(2)BCHMeCHPhNHPh were synthes ized by the reaction of Mes(2)BCHMeLi with N-benzylideneaniline. The s tereochemistry was determined by chemical derivation into the correspo nding cyclic carbamates via beta-amino alcohols. Their thermolysis gav e a mixture of the corresponding (E)-enamine and its tautomer, (E)-imi ne, in sharp contrast to that of beta-hydroxy boranes giving the olefi ns.