CONVERSION OF THIOCYANATES INTO DISULFIDES - AN APPROACH TO POLY(VINYLENE DISULFIDE) AND RELATED DERIVATIVES FROM (E)-1,2-DITHIOCYANATOALKENES

Authors
GIFFARD M BUISSON JP BUSNEL JP GODON C LEFRANT S NGUYEN TP
Citation
M. Giffard et al., CONVERSION OF THIOCYANATES INTO DISULFIDES - AN APPROACH TO POLY(VINYLENE DISULFIDE) AND RELATED DERIVATIVES FROM (E)-1,2-DITHIOCYANATOALKENES, Journal of chemical research. Synopses, (3), 1993, pp. 126-127
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
3
Year of publication
1993
Pages
126 - 127
Database
ISI
SICI code
0308-2342(1993):3<126:COTID->2.0.ZU;2-T
Abstract
(E)-1,2-Dithiocyanatoalkenes R-C(SCN)=CH-SCN (R = H, Bu(n), Ph) can be converted into ethylenic polydisulfides of the type -[S-CR=CH-S]n- by the action of potassium hydroxide and potassium hexacyanoferrate(III) in aqueous medium; these polymers become semiconducting upon chemical doping.