COORDINATION-DEPENDENT EQUATION OF STATE OF EXPANDED LIQUID ALKALI-METALS AND CRITICAL-POINT PROPERTIES

Authors
MARCH NH TOSI MP
Citation
Nh. March et Mp. Tosi, COORDINATION-DEPENDENT EQUATION OF STATE OF EXPANDED LIQUID ALKALI-METALS AND CRITICAL-POINT PROPERTIES, Physics and chemistry of liquids, 29(3), 1995, pp. 197-199
Citations number
6
Categorie Soggetti
Chemistry Physical","Physics, Condensed Matter
Journal title
Physics and chemistry of liquids → ACNP
ISSN journal
00319104
Volume
29
Issue
3
Year of publication
1995
Pages
197 - 199
Database
ISI
SICI code
0031-9104(1995)29:3<197:CEOSOE>2.0.ZU;2-R
Abstract
To take account of the known structure of expanded heavy alkali metals , a coordination number-dependent equation of stare is set up. It is t hen shown that the critical constants T-c and V-c. are related by TcV1 /3 = constant, while the compressibility ratio is no longer constant t hrough the alkali series, as required by experiment.