EXCESS VOLUMES AND EXCESS VISCOSITIES OF BINARY-MIXTURES OF CYCLOHEXANE PLUS AN ISOMER OF BUTANOL AT SEVERAL TEMPERATURES

Citation
H. Artigas et al., EXCESS VOLUMES AND EXCESS VISCOSITIES OF BINARY-MIXTURES OF CYCLOHEXANE PLUS AN ISOMER OF BUTANOL AT SEVERAL TEMPERATURES, Physics and chemistry of liquids, 30(1), 1995, pp. 17-28
Citations number
11
Categorie Soggetti
Chemistry Physical","Physics, Condensed Matter
ISSN journal
00319104
Volume
30
Issue
1
Year of publication
1995
Pages
17 - 28
Database
ISI
SICI code
0031-9104(1995)30:1<17:EVAEVO>2.0.ZU;2-3
Abstract
From density and viscosity measurements of binary mixtures of cyclohex ane with an isomer of butanol at several temperatures, excess volumes V-E, excess viscosities eta(E) and excess energies of activation for V iscous flow G(E) have been determined at different temperatures. The results have been correlated by a Redlich-Kister type equation and dis cussed in terms of molecular interactions. While V-E values are positi ve over the whole composition range for all mixtures at all temperatur es, both eta(E) and G(E) are negative.