H. Artigas et al., EXCESS VOLUMES AND EXCESS VISCOSITIES OF BINARY-MIXTURES OF CYCLOHEXANE PLUS AN ISOMER OF BUTANOL AT SEVERAL TEMPERATURES, Physics and chemistry of liquids, 30(1), 1995, pp. 17-28
From density and viscosity measurements of binary mixtures of cyclohex
ane with an isomer of butanol at several temperatures, excess volumes
V-E, excess viscosities eta(E) and excess energies of activation for V
iscous flow G(E) have been determined at different temperatures. The
results have been correlated by a Redlich-Kister type equation and dis
cussed in terms of molecular interactions. While V-E values are positi
ve over the whole composition range for all mixtures at all temperatur
es, both eta(E) and G(E) are negative.