Using X-ray diffraction, structure factors and pair correlation functi
ons of molten Bi-Pb alloys were determined. As well the calculated Deb
ye temperatures as the partial pair correlation functions obtained wit
h the concentration method indicate that alterations of the short rang
e order due to a reduction of unlike atomic pairs with rising temperat
ure take place. Moreover, the properties of the melt dependent on temp
erature can be explained ii the existence of associates like the perit
ectically melting epsilon-phase is assumed.