M. Vandevyver et al., OUT OF PLANE AXIAL REORGANIZATION AND PHASE-CHANGE IN LANGMUIR-BLODGETT-FILMS OF A MESOMORPHIC SIDE-CHAIN POLYMER, Journal of physics. D, Applied physics, 26(4), 1993, pp. 686-689
Langmuir-Blodgett films built of a mesomorphic side chain polymethacry
late are investigated from the point of view of their phase changes ag
ainst temperature. With heating, a strong 'out of plane' molecular reo
rganization towards a smectic phase takes place giving rise to an incr
ease of the order parameter.