CHEMISTRY OF SILYL THIOKETONES .9. A NEW SELECTIVE SYNTHESIS OF 1-SILYL-1-ENETHIOLS AND OF 2-SILYL-THIACYCLOALK-2-ENES OF COMMON TO LARGE RING SIZE

Authors
BONINI BF COMESFRANCHINI M FOCHI M MAZZANTI G RICCI A
Citation
Bf. Bonini et al., CHEMISTRY OF SILYL THIOKETONES .9. A NEW SELECTIVE SYNTHESIS OF 1-SILYL-1-ENETHIOLS AND OF 2-SILYL-THIACYCLOALK-2-ENES OF COMMON TO LARGE RING SIZE, Tetrahedron, 52(13), 1996, pp. 4803-4816
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
13
Year of publication
1996
Pages
4803 - 4816
Database
ISI
SICI code
0040-4020(1996)52:13<4803:COST.A>2.0.ZU;2-4
Abstract
omega-Haloacylsilanes 1 were selectively transformed via thioacylsilan es into Z-silyl-enethiols 4 with solid sodium hydrogen carbonate or in to 2-silylthiacycloalk-2-ene 5 of common to large ring size with solid sodium hydroxide. Compounds 5 underwent protiodesilylation.