TRICARBONYL(ETA(6)ARENE)CHROMIUM(0) COMPLEXES AS CHIRAL AUXILIARIES -ASYMMETRIC-SYNTHESIS OF BETA-AMINOESTERS AND BETA-LACTAMS BY REFORMATSKY CONDENSATION

Authors
BALDOLI C DELBUTTERO P LICANDRO E PAPAGNI A PILATI T
Citation
C. Baldoli et al., TRICARBONYL(ETA(6)ARENE)CHROMIUM(0) COMPLEXES AS CHIRAL AUXILIARIES -ASYMMETRIC-SYNTHESIS OF BETA-AMINOESTERS AND BETA-LACTAMS BY REFORMATSKY CONDENSATION, Tetrahedron, 52(13), 1996, pp. 4849-4856
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
13
Year of publication
1996
Pages
4849 - 4856
Database
ISI
SICI code
0040-4020(1996)52:13<4849:TCACA->2.0.ZU;2-M
Abstract
Highly stereoselective syntheses (e.e. > 98%) of beta-aminoesters and beta-lactams were accomplished using enantiomerically pure tricarbonyl (eta(6)benzaldimine)chromium complexes in a Reformatsky type reaction promoted by ultrasound. A correlation between the configuration of co mplexed imines and absolute configuration of beta-lactam derivatives i s reported.