Hq. Xie et Jg. Guan, STUDY ON ELECTRORHEOLOGICAL PROPERTIES OF SEMICONDUCTING POLYANILINE-BASED SUSPENSIONS, Die Angewandte makromolekulare Chemie, 235, 1996, pp. 21-34
Electrorheological (ER) fluids composed of a dispersing medium with a
low dielectric constant and polyaniline particles, deprotonated with a
mmonia or sodium hydroxide at different concentrations for 24 h were s
tudied. The effects of dielectric constant, conductivity and volume fr
action of the polyaniline particles, the kind of dispersing medium, ad
dition of surfactant, as well as the electric field strength and tempe
rature on the ER properties of the ER fluids were investigated. The re
sults showed that a moisture-insensitive, highly ER-active fluid can b
e obtained from chlorinated paraffin oil and polyaniline particles dep
rotonated with ammonia water at certain pH values and exhibited a stat
ic yield stress >10 kPa and current density <40 mu A cm(-2) at 2.8 kV
mm(-1) DC electric field.