SYNTHESIS AND PROPERTIES OF COPPER(II) AND OXOVANADIUM(IV) COMPLEXES DERIVED FROM POLAR SCHIFFS BASES

Authors
CAMPILLOS E MARCOS M OMENAT A SERRANO JL
Citation
E. Campillos et al., SYNTHESIS AND PROPERTIES OF COPPER(II) AND OXOVANADIUM(IV) COMPLEXES DERIVED FROM POLAR SCHIFFS BASES, Journal of materials chemistry, 6(3), 1996, pp. 349-355
Citations number
21
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
6
Issue
3
Year of publication
1996
Pages
349 - 355
Database
ISI
SICI code
0959-9428(1996)6:3<349:SAPOCA>2.0.ZU;2-8
Abstract
The synthesis and mesogenic behaviour of copper(II) and oxovanadium(IV ) complexes derived from Schiff's bases substituted with polar groups and of their corresponding ligands are reported. The polar groups stud ied are F, CF3, CN, and CH2CN in the 3 or 4 position of the aniline mo iety. The ligands exhibited smectic C, smectic A and nematic phases, w hereas the complexes showed smectic A and nematic phases, and in some cases oxovanadium(IV) complexes exhibited a smectic crystal phase.