T. Muro et al., MAGNETIC CIRCULAR-DICHROISM OF THE S-2P, CO-2P, AND CO-3P CORE ABSORPTION AND ORBITAL ANGULAR-MOMENTUM OF THE CO-3D STATE IN LOW-SPIN COS2, Physical review. B, Condensed matter, 53(11), 1996, pp. 7055-7058
Magnetic circular dichroism (MCD) has been measured for ferromagnetic
CoS2 in the S 2p, Co 2p and 3p core absorption regions. MCD in the S 2
p region is discussed in terms of the exchange splitting of the unoccu
pied band. The Co 2p MCD has revealed that the orbital angular momentu
m of the Co 3d state remains finite in spite of its low-spin configura
tion. This situation is confirmed by a simple cluster model calculatio
n.