We investigate a class of two-dimensional hexagonal structures that po
ssess photonic band gaps. This class includes the previously studied t
riangular structure as a particular case. By symmetry analysis, we obt
ain a clear insight into the gap opening and we show how the photonic
band gaps are affected by the characteristics of materials, according
to whether the dielectric constant of the cylinders is larger or small
er than the background one. The photonic band structures present numer
ous gaps, and we study the evolution of these gaps as functions of the
diameter and nature of cylinders. Our results demonstrate the existen
ce of absolute band gaps for many configurations, largest gaps being o
btained for triangular and graphite structures.