PREPARATION OF SUBSTITUTED VINYLSILANES FROM CINNAMYL CARBAMATES

Authors
MASON PH EMSLIE ND
Citation
Ph. Mason et Nd. Emslie, PREPARATION OF SUBSTITUTED VINYLSILANES FROM CINNAMYL CARBAMATES, Synthetic communications, 26(8), 1996, pp. 1473-1483
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
26
Issue
8
Year of publication
1996
Pages
1473 - 1483
Database
ISI
SICI code
0039-7911(1996)26:8<1473:POSVFC>2.0.ZU;2-P
Abstract
Reaction of N,N-diethyl cinnamyl carbamate with TBDMSCl yields the mon o-silylated carbamate which, on treatment with butyllithium, reacts wi th various electrophiles to give the corresponding disubstituted carba mates.