SYNTHESIS OF A MEXICAN BEAN BEETLE AZAMACROLIDE ALLOMONE VIA A NOVEL LACTAM TO LACTONE RING EXPANSION

Citation
Gw. Gribble et Ra. Silva, SYNTHESIS OF A MEXICAN BEAN BEETLE AZAMACROLIDE ALLOMONE VIA A NOVEL LACTAM TO LACTONE RING EXPANSION, Tetrahedron letters, 37(13), 1996, pp. 2145-2148
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
37
Issue
13
Year of publication
1996
Pages
2145 - 2148
Database
ISI
SICI code
0040-4039(1996)37:13<2145:SOAMBB>2.0.ZU;2-0
Abstract
The Mexican bean beetle (Epilachna varivestis) defensive secretion aza macrolide 1 has been synthesized via the novel ring expansion of N-hyd roxyethyl lactam 12, which was prepared in seven steps from cyclooctan one (6).