A NOVEL INTRAMOLECULAR DECARBOXYLATIVE GLYCOSYLATION VIA MIXED CARBONATE

Authors
IIMORI T SHIBAZAKI T IKEGAMI S
Citation
T. Iimori et al., A NOVEL INTRAMOLECULAR DECARBOXYLATIVE GLYCOSYLATION VIA MIXED CARBONATE, Tetrahedron letters, 37(13), 1996, pp. 2267-2270
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
13
Year of publication
1996
Pages
2267 - 2270
Database
ISI
SICI code
0040-4039(1996)37:13<2267:ANIDGV>2.0.ZU;2-3
Abstract
A two-step glycosylation procedure, which involves (1) linking two sug ars by using carbonate as a connector, (2) removing carbon dioxide to form a glycosidic bond by the aid of Lewis acid, has been developed. T his glycosylation procedure was based on the opposite mode of connecti on, where a glycosyl acceptor was activated to link sugars.