Basic electrochemical characteristics of 1-benzyl-tetrazole-5-thiol in
acid medium were investigated applying classical (DC) polarography, c
yclic (CV) and square-wave voltammetry (SWV). During the HMDE life-tim
e, a compound was spontaneously formed between the mercury and thiol a
nd deposited on the HMDE surface. The surface precipitation process re
sults in formation of a multilayer film on the electrode surface. The
SW response of the investigated component mainly depends on the struct
ure of the film.