B. Gady et al., IDENTIFICATION OF ELECTROSTATIC AND VAN-DER-WAALS INTERACTION FORCES BETWEEN A MICROMETER-SIZE SPHERE AND A FLAT SUBSTRATE, Physical review. B, Condensed matter, 53(12), 1996, pp. 8065-8070
The interaction force gradient between a micron-size polystyrene spher
e and an atomically hat highly oriented pyrolytic graphite substrate h
as been analyzed as a function of surface-to-surface separation distan
ce z(0) using an oscillating cantilever technique. The interaction for
ce gradient was found to have two contributions. For z(0) greater than
or equal to 30 nm, an electrostatic force due to charges trapped on t
he polystyrene sphere dominates. For z(0) less than or equal to 30 nm,
a van der Waals interaction, characteristic of a sphere near a flat p
lane, is observed. Fits to the data are in good agreement with theoret
ical expectations and allow estimates of the surface charge density tr
iboelectrically produced on the sphere's surface.