Dl. Orth et al., OPTICAL LINESHAPES OF IMPURITIES IN CRYSTALS - A LATTICE MODEL OF INHOMOGENEOUS BROADENING BY POINT-DEFECTS, Journal of physics. Condensed matter, 5(16), 1993, pp. 2533-2544
Previous theories of inhomogeneous broadening by point defects of impu
rity transitions in crystals have invoked a continuum approximation fo
r the defect positions. We generalize these theories by treating the c
rystal as a discrete lattice. At low defect densities we recover the r
esults of the continuum theory, finding a Lorentzian lineshape. At hig
h defect densities the lineshape is approximately Gaussian. At interme
diate densities, the lineshape displays satellite structure due to dif
ferent configurations of nearby defects. For all densities we derive a
pproximate analytic expressions for the lineshape that are in good agr
eement with exact numerical results.