THE SYNTHESES AND CHARACTERIZATION OF GENOBIS(N,N-DIALKYLTHIO-CARBAMOYL)SULFIDOCOPPER(I)

Authors
VICTORIANO LI CORTES H
Citation
Li. Victoriano et H. Cortes, THE SYNTHESES AND CHARACTERIZATION OF GENOBIS(N,N-DIALKYLTHIO-CARBAMOYL)SULFIDOCOPPER(I), Journal of coordination chemistry, 36(2), 1995, pp. 159-166
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry → ACNP
ISSN journal
00958972
Volume
36
Issue
2
Year of publication
1995
Pages
159 - 166
Database
ISI
SICI code
0095-8972(1995)36:2<159:TSACOG>2.0.ZU;2-U
Abstract
Tetraalkylthiuram monosulfides react with Cu(I) halides to form 1:1 ad ducts, which are characterized by IR, Raman and H-1-NMR spectroscopy, as well as magnetic susceptibility, molecular weight and conductivity measurements. The compounds are monomers or dimers, according to the n ature of the alkyl substituent. The molecules in solution exist as equ ilibrium mixtures of monomers and dimers.