STUDIES OF THE SEGREGATION DEPENDENCE OF PROTON KNIGHT-SHIFTS IN RU-CU BIMETALLICS

Authors
KHANRA BC KING TS
Citation
Bc. Khanra et Ts. King, STUDIES OF THE SEGREGATION DEPENDENCE OF PROTON KNIGHT-SHIFTS IN RU-CU BIMETALLICS, Journal of physical chemistry, 97(16), 1993, pp. 4164-4166
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
97
Issue
16
Year of publication
1993
Pages
4164 - 4166
Database
ISI
SICI code
0022-3654(1993)97:16<4164:SOTSDO>2.0.ZU;2-X
Abstract
The concentration dependence of proton Knight shifts associated with c hemisorbed hydrogen on Ru-Cu bimetallics has been studied in terms of conduction electron polarization and surface segregation. Comparison o f the calculated results with the experimental results suggests that t he proton Knight shift for Ru-Cu particles results mainly from the hyd rogen atoms experiencing a hyperfine interaction with three Ru first n earest neighbors.