In this study we investigate numerical simulations of one-dimensional
water flow and solute transport in a soil with a nonuniform pore-size
distribution, Water transport was modeled by treating the soil as one
domain by applying Richards equation, while using alternatively a unim
odal and a bimodal model for the hydraulic properties. The retention c
urves were fitted to a set of measured data; the relative conductivity
functions were estimated by Mualem's [1976] model. Contrary to the un
imodal case, the bimodal conductivity curve shows a steep decrease in
water content theta near saturation. Simulated water regimes under tra
nsient boundary conditions differed strongly fur the two cases. The us
e of the bimodal functions yielded a preferential flow characteristic
which was not obtained using unimodal functions. For both hydraulic re
gimes we modeled solute transport comparing four different variants of
the convection-dispersion equation. For the classical one-region mode
l we found that the breakthrough curve of an ideal tracer was not affe
cted by the dynamics of the water flow. For the two-region approach, w
here the water-filled pore domain is divided into a mobile region thet
a(m) and an immobile region theta(im), three different conceptual trea
tments of theta(m) under transient conditions were investigated. For t
he case where theta(im) was kept constant, the different hydraulic reg
imes again caused only minor differences in solute transport. The same
was true for the alternative case where the ratio theta(m)/theta was
kept constant. However, for the third case, where theta(m) was treated
as a dynamic variable which changes with the actual water content in
a way that depends on the shape of the hydraulic conductivity function
, the transport simulation based on the bimodal hydraulic model reflec
ted enhanced preferential transport at high-infiltration rates.