PREPARATION, B-11, C-13, H-1-NMR AND VIBR ATIONAL-SPECTRA OF MU-PENTAMETHYLENE-BIS-HEXAHYDRO-CLOSO-HEXABORATE, [B6H6(CH2)(5)B6H6](2-), AND MU-HEXAMETHYLENE-BIS-HEXAHYDRO-CLOSO-HEXABORATE, [B6H6(CH2)(6)B6H6](2-)

Authors
LUBBE W PREETZ W
Citation
W. Lubbe et W. Preetz, PREPARATION, B-11, C-13, H-1-NMR AND VIBR ATIONAL-SPECTRA OF MU-PENTAMETHYLENE-BIS-HEXAHYDRO-CLOSO-HEXABORATE, [B6H6(CH2)(5)B6H6](2-), AND MU-HEXAMETHYLENE-BIS-HEXAHYDRO-CLOSO-HEXABORATE, [B6H6(CH2)(6)B6H6](2-), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 51(3), 1996, pp. 359-362
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
51
Issue
3
Year of publication
1996
Pages
359 - 362
Database
ISI
SICI code
0932-0776(1996)51:3<359:PBCHAV>2.0.ZU;2-3
Abstract
In the reaction of [B6H6](2-) With diiodopentane or diiodohexane in di chloromethane mu-pentamethplene-bis-hexahydro-closo-hexaborate [B6H6(C H2)(5)B6H6](2-) (I), and mu-hexamethylene-bishexahydro-closo-hexaborat e, [B6H6(CH2)(6)B6H6](2-) (II), are formed, respectively. The products were separated from excess [B6H6](2-) by ion exchange chromatography on diethylaminoethyl cellulose and have been identified and characteri zed by B-11, C-13, H-1 NMR and vibrational spectroscopy.