A FACILE LIPASE-CATALYZED ACCESS TO FATTY-ACID MONOESTERS OF 2-O-BETA-D-GLUCOSYLGLYCEROL

Authors
COLOMBO D RONCHETTI F SCALA A TAINO IM TOMA L
Citation
D. Colombo et al., A FACILE LIPASE-CATALYZED ACCESS TO FATTY-ACID MONOESTERS OF 2-O-BETA-D-GLUCOSYLGLYCEROL, Tetrahedron : asymmetry, 7(3), 1996, pp. 771-777
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
3
Year of publication
1996
Pages
771 - 777
Database
ISI
SICI code
0957-4166(1996)7:3<771:AFLATF>2.0.ZU;2-0
Abstract
2-O-beta-D-glucopyranosylglycerol was submitted to acylation using Pse udomonas cepacia lipase as catalyst and 2,2,2-trifluoroethyl esters of various long chain carboxylic acids as acyl carriers. Monoacylation w as easily accomplished with preferred formation of the (2S)-1-O-acyl d erivatives in reactions showing high regio- and diastereoselectivity. (C) 1996 Elsevier Science Ltd