The surface electronic structure of the clean Si(100)-(2x1) surface at
room temperature is studied by high-resolution electron-energy-loss s
pectroscopy. Main absorption edge is detected at similar to 0.4 eV, wh
ich corresponds to the energy gap of the system, further structures ar
e singled out at 0.8 and 1.25 eV and ascribed to interband electronic
transitions between dimer-related levels. The paramount importance of
cleanness is addressed showing and quantifying the effect of the resid
ual gas atmosphere (that can be present in ultrahigh vacuum) on the el
ectronic structure.