C. Henig et al., ELECTRON CORRELATION IN MNO(100) - A COMPARISON OF SXAPS AND CEELS SPECTRA, Journal of electron spectroscopy and related phenomena, 76, 1995, pp. 547-551
Unoccupied states of the correlated insulator MnO(100) have been inves
tigated by core electron energy loss (CEELS) and appearance potential
spectroscopy (APS) at the manganese 2p and oxygen Is threshold. The sp
ectra show the dominant role of the empty manganese 3d states when cor
e electrons are excited near the threshold. A comparison of both spect
roscopies should give the possibility to evaluate the magnitude of the
electron correlation U-dd. But at the oxygen Is threshold, no influen
ce of the correlation is recognizable because here the ligand CEELS an
d SXAPS spectra are similar to a large extent. However, CEELS and SXAP
S at the manganese 2p threshold show different structures.