K. Wolski et al., OXIDE TRANSFORMATIONS DURING SINTERING OF IN-SITU OXIDIZED FEAL POWDERS, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 207(1), 1996, pp. 105-114
Powder metallurgy has been used to prepare FeAI powders with in situ c
reated oxidation products. The aim of this study was to analyse the ty
pes of oxide formed as a function of sintering conditions. Highly oxid
ised powders have been used to give evidence of these transformations
by X-ray diffraction. It has been shown that low temperature sintering
(T< 1200 degrees C) results in the formation of FeAl2O4 spinel, while
higher sintering temperatures lead to its transformation into alpha-A
l2O3 and coarsening. An attempt, based on thermodynamic calculations,
has been made to explain the formation of FeAl2O4 spinel.