An accurate measurement of the Doppler effect in collinear laser spect
roscopy has been performed at the TSR storage ring with electron coole
d Li-7(+) ions at beta = 0.064. This experiment is a sensitive test of
the gamma = (1 - beta(2))(-1/2) factor(beta = upsilon/c) in the speci
al theory of relativity. The Doppler shifted frequencies of the moving
Li-7(+) ions are compared with calibrated molecular lines at rest. Th
e frequencies at rest for the Li-7(+) ions are known from independent
measurements. The Doppler shifted frequencies in the collinear experim
ent have been measured with a precision of Delta v/v = 6 x 10(-9), mai
nly limited by the signal width of the resonance. A corresponding uppe
r limit of 8 x 10(-7) is deduced for any deviation of the time dilatat
ion factor gamma in special theory of relativity. A still higher accur
acy is expected with a laser cooled ion beam. If such a beam is simult
aneously subjected to RF bunching, the particle velocity and phase are
exactly known. With an additional high resolution laser frequency mea
surement an improvement of at least one order of magnitude may be achi
eved.