A generalized modeling framework for process synthesis alternatives is
proposed, based on fundamental mass/heat-transfer principles. A multi
purpose mass/heat-transfer module is introduced as the building block
of the framework, whereas basic block-superstructure rules (such as sp
litting, mixing, and bypassing) ave used to develop a systematic repre
sentation of process units and process structures, conventional or not
. Process synthesis procedures ave explored within this modeling frame
work,, where synthesis alternatives are not postulated as process unit
networks, but explored simultaneously without predefining synthesis s
chemes, as combinations of mass/heat-exchange stream matches. The repr
esentation potential of this framework is illustrated with examples fr
om unit operations whereas synthesis example problems are presented to
show the broad range of process alternatives that can be modeled iden
tified and optimized.