NOVEL CATIONIC CHIRAL PHOSPHORUS LIGANDS AND THEIR ZWITTERIONIC HYDRIDOCARBONYLFERRATE COMPLEXES

Authors
BRUNET JJ CHAUVIN R COMMENGES G DONNADIEU B LEGLAYE P
Citation
Jj. Brunet et al., NOVEL CATIONIC CHIRAL PHOSPHORUS LIGANDS AND THEIR ZWITTERIONIC HYDRIDOCARBONYLFERRATE COMPLEXES, Organometallics, 15(7), 1996, pp. 1752-1754
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
7
Year of publication
1996
Pages
1752 - 1754
Database
ISI
SICI code
0276-7333(1996)15:7<1752:NCCPLA>2.0.ZU;2-X
Abstract
The reaction of (-)-N,N-dimethylephedrinium salts with R(2)PNMe(2) der ivatives allows the high-yield synthesis of new chiral phosphorus liga nds with an ammonium side chain, termed ''ephosiums''. Diphenyl-N,N-di methylephosium hexaflurophosphate reacts with KHFe(CO)(4) to afford th e chiral zwitterionic complex diphenyl-N,N-dimethylephosium hydridotri carbonylferrate, characterized by X-ray diffraction and NMR studies.