ORGANOMETALLIC COMPLEXES FOR NONLINEAR OPTICS .3. MOLECULAR QUADRATICHYPERPOLARIZABILITIES OF ENE-LINKED, IMINE-LINKED, AND AZO-LINKED RUTHENIUM SIGMA-ACETYLIDES - X-RAY CRYSTAL-STRUCTURE OF (E)-4,4'-C-CC6H4CH=CHC6H4NO2)(PPH(3))(2)(ETA-C5H5)
Ir. Whittall et al., ORGANOMETALLIC COMPLEXES FOR NONLINEAR OPTICS .3. MOLECULAR QUADRATICHYPERPOLARIZABILITIES OF ENE-LINKED, IMINE-LINKED, AND AZO-LINKED RUTHENIUM SIGMA-ACETYLIDES - X-RAY CRYSTAL-STRUCTURE OF (E)-4,4'-C-CC6H4CH=CHC6H4NO2)(PPH(3))(2)(ETA-C5H5), Organometallics, 15(7), 1996, pp. 1935-1941
The series of complexes E)-4,4'-C=CC(6)H(4)X=CHC6H4NO2)PR(3))(2)(eta-C
5H5) (X = CH, R = Ph, 11a; X = CH, R = Me, 11b; X = N, R = Ph, 12a; X
= N, R = Me, 12b) has been synthesized by reaction of RuCl(PR(3))(2)(e
ta-C5H5) with (E)-4,4'-HC=CC(6)H(4)X=CHC6H4NO2 and deprotonation of th
e intermediate vinylidene complex. Complex 11a has been structurally c
haracterized; it is the first example of a donor-acceptor organometall
ic ''extended'' chromophore bearing the prototypical acceptor -NO2 to
be crystallographically studied. Molecular quadratic hyperpolarizabili
ties at 1.9 mu m were evaluated computationally for the complexes abov
e and imine- and ate-linked analogues by employing ZINDO with crystall
ographically obtained atomic coordinates. The results are consistent w
ith a substantial increase in quadratic nonlinearity for (i) chain len
gthening of the organometallic chromophore (replacing 4-C=CC6H4NO2 by
(E)-4,4'-C=CC6H4CH=CHC6H4NO2) and (ii) an azo linkage compared with an
ene linkage (replacing (E)-4,4'-C=CC6H4CH=CHC6H4NO2 by (E)-4,4'C=CC6H
4N=NC6H4NO2). Little variation in computed response was found upon sub
stituting an imine linkage for an ene Linkage in the organometallic ch
romophore (replacing (E)-4,4'-C=CC6H4CH=CHC6H4NO2 by (E)-4,4'-C=CC6H4N
=CHC6H4NO2 or (E)-4,4'-C=CC6H4-CH=NC6H4NO2). Molecular quadratic optic
al nonlinearities were determined experimentally for 11a, 12a, and Ru(
C=CC6H4NO2-4 (PR(3))(2)(eta-C5H5) (R = Ph, Me) by electric-field-induc
ed second-harmonic generation(EFISH; 11a and 12a only) and hyper-Rayle
igh scattering (HRS) techniques, EFISH-derived mu beta(1064) values fo
r 11a (9700 x 10(-48) cm(5) esu(-1)) and 12a (5800 x 10(-48) cm(5) esu
(-1)) are large compared to those for other organometallic complexes.
Resonance-enhanced quadratic nonlinearities at 1.06 mu m from HRS are
large (1455 x 10(-30) cm(5) esu(-1), 11a; 840 x 10(-30) cm(5) esu(-1),
12a). Two-level-corrected values confirm a substantial increase in qu
adratic nonlinearity for chain lengthening but suggest a significant d
ecrease in nonlinearity on replacing an ene linkage by an imine linkag
e; the latter is contrary to the ZINDO result, and the reasons for thi
s are discussed.