THE 2-NU(5) OVERTONE BAND OF CYANOACETYLENE BY HIGH-RESOLUTION FTIR SPECTROSCOPY

Authors
YAMADA KMT MORAVEC A NIEDENHOFF M BURGER H WINNEWISSER G
Citation
Kmt. Yamada et al., THE 2-NU(5) OVERTONE BAND OF CYANOACETYLENE BY HIGH-RESOLUTION FTIR SPECTROSCOPY, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 51(1-2), 1996, pp. 27-35
Citations number
16
Categorie Soggetti
Chemistry Physical",Physics
Journal title
Zeitschrift fur Naturforschung. A, A journal of physical sciences → ACNP
ISSN journal
09320784
Volume
51
Issue
1-2
Year of publication
1996
Pages
27 - 35
Database
ISI
SICI code
0932-0784(1996)51:1-2<27:T2OBOC>2.0.ZU;2-Z
Abstract
The 2 nu(5) overtone band of cyanoacetylene, HCCCN, has been measured with a high resolution FTIR spectrometer. The analysis of the accident al resonances results in very accurate parameters for the observed ups ilon(5), = 2 state as well as for the hidden perturber state (upsilon( 4) = 1, upsilon(7) = 2); the vibrational energy and the relational con stant have been determined to be 1312.991921(23) cm(-1) and 4552.38440 (23) MHz for the upsilon(5) = 2 state, and 1310.0627(6) cm(-1) and 457 2.463(4) MHz for the (upsilon(4) = 1, upsilon(7) = 2) state. The assoc iated hot bands from the upsilon(7) = 1, upsilon(6) = 1, and upsilon(5 ) = 1 state have also been analyzed.