The interfacial reaction product Al4C3 in Gr/Al composites was shown p
referentially nucleated on graphite surface where attachments or amorp
hous carbon exist. No definite orientation relationship of Al4C3 with
base graphite fiber was found in the present investigation. On the oth
er hand, three different orientation relationships were established be
tween Al4C3 and the surrounding aluminum matrix. The morphology of Al4
C3, which was found to be controlled by processing conditions, is inte
rpreted in terms of the extent and nature of two different growth cont
rol mechanisms. The concentration gradient of carbon in the aluminum m
atrix near graphite fiber surface was found. The carbon atoms for the
growth of Al4C3 are considered to be supplied through the aluminum mat
rix along this concentration gradient.