Atomically resolved scanning tunneling microscope images of Si cluster
s deposited onto a Si(111)-7 x 7 substrate have been obtained. The clu
sters display a capping layer of widely spaced surface atoms analogous
to the reconstructed surface of a bulk crystal. Site-specific variati
ons in the electronic characteristics of cluster surface atoms are det
ected. Adsorption studies demonstrate size dependant reactivity of dep
osited clusters. Clusters are observed to collapse upon annealing to f
orm epitaxial Si islands.