ON THE CALCULATION OF SHAKE-OFF SATELLITE CONTRIBUTIONS TO MOLECULAR AUGER-SPECTRA

Authors
HANDKE G TARANTELLI F CEDERBAUM LS
Citation
G. Handke et al., ON THE CALCULATION OF SHAKE-OFF SATELLITE CONTRIBUTIONS TO MOLECULAR AUGER-SPECTRA, Chemical physics letters, 251(1-2), 1996, pp. 26-32
Citations number
37
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
251
Issue
1-2
Year of publication
1996
Pages
26 - 32
Database
ISI
SICI code
0009-2614(1996)251:1-2<26:OTCOSS>2.0.ZU;2-Q
Abstract
An efficient approach to calculate shake-off satellite contributions t o molecular Auger spectra is presented. The vertical ab initio energie s of the transition to the triply ionized final states of the shake-of f process are calculated by a Green's function method. An estimate of the Auger transition rates based on an analysis of the hole localizati on in the final states is used for a theoretical simulation of the spe ctrum. The method is applied to the Auger spectrum of LiF.