Av. Glushkov et al., CALCULATION OF INTERACTION POTENTIALS FOR EXCITED ALKALI ATOM-MERCURYATOM SYSTEMS - THE K-ASTERISK-HG INTERACTION, Journal of structural chemistry, 36(4), 1995, pp. 551-556
Interatomic potentials for the systems alkali atom (in the ground and
excited states)-mercury atom are calculated by the effective potential
method using a polarization potential obtained from calculation of mo
st important polarization diagrams of perturbation theory in the Thoma
s-Fermi approximation. The results are used to calculate the quasimole
cular terms of the A-Hg systems, where A = Na, K. Some values of the i
nteraction potential parameters are published for the first time. The
results obtained in this work are compared with the available experime
ntal and theoretical data.