CALCULATION OF INTERACTION POTENTIALS FOR EXCITED ALKALI ATOM-MERCURYATOM SYSTEMS - THE K-ASTERISK-HG INTERACTION

Citation
Av. Glushkov et al., CALCULATION OF INTERACTION POTENTIALS FOR EXCITED ALKALI ATOM-MERCURYATOM SYSTEMS - THE K-ASTERISK-HG INTERACTION, Journal of structural chemistry, 36(4), 1995, pp. 551-556
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
ISSN journal
00224766
Volume
36
Issue
4
Year of publication
1995
Pages
551 - 556
Database
ISI
SICI code
0022-4766(1995)36:4<551:COIPFE>2.0.ZU;2-L
Abstract
Interatomic potentials for the systems alkali atom (in the ground and excited states)-mercury atom are calculated by the effective potential method using a polarization potential obtained from calculation of mo st important polarization diagrams of perturbation theory in the Thoma s-Fermi approximation. The results are used to calculate the quasimole cular terms of the A-Hg systems, where A = Na, K. Some values of the i nteraction potential parameters are published for the first time. The results obtained in this work are compared with the available experime ntal and theoretical data.