STRUCTURE AND COMPOSITION OF THE POLYMERIC PRODUCTS OF UO2SO4 EXTRACTION BY BENZENE SOLUTIONS OF URANYL BIS(2-ETHYLHEXYL) PHOSPHATE

Authors
STOYANOV ES MIKHAILOV VA TORGOV VG US TV
Citation
Es. Stoyanov et al., STRUCTURE AND COMPOSITION OF THE POLYMERIC PRODUCTS OF UO2SO4 EXTRACTION BY BENZENE SOLUTIONS OF URANYL BIS(2-ETHYLHEXYL) PHOSPHATE, Journal of structural chemistry, 36(4), 1995, pp. 619-625
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
36
Issue
4
Year of publication
1995
Pages
619 - 625
Database
ISI
SICI code
0022-4766(1995)36:4<619:SACOTP>2.0.ZU;2-C
Abstract
UO2SO4 extracts obtained from neutral aqueous solutions of this compou nd and benzene solutions of uranyl bis(2-ethylhexyl) phosphate have be en studied by P-31 NMR and IR spectroscopy. It has been found that in the presence of donor-active additions L = TBP or DOSO the recurrent u nit of the polymer (UO(2)X(2))(p) adds one or two UO2O4 molecules to f orm (UO(2)X(2).UO2SO4.2L) and (UO(2)X(2).2UO(2)SO(4).6L) units. The st ructure of these units has been established. If has been shown that th e distribution of UO2SO4 molecules along the polymer chain is random.