E. Aharoni et al., BARRIER AND ELECTRODE PROPERTIES OF HIGH T(C) JOSEPHSON-JUNCTIONS FORMED BY A PLASMA DISCHARGE PROCESS, Physica. C, Superconductivity, 209(1-3), 1993, pp. 215-218
The influence of rf discharge in CF4 and O2 gases on the properties of
thin YBCO films and edge junctions was investigated by transport meas
urement and Auger spectroscopy. It was found that oxygen plasma of sho
rt duration can serve as a cleaning step before the formation of the b
arrier. In contrast, CF4 plasma tends to substitute oxygen in the supe
rconducting film by fluorine which yield an insulating layer. A CF4 pl
asma discharge of more than one minute turns the YBCO film irreversibl
y into an insulator. At shorter durations, the deterioration of the fi
lms is limited to a thickness of the order of few tens of angstroms.