Hs. Helmisaari et al., COPPER IN SCOTS PINE FORESTS AROUND A HEAVY-METAL SMELTER IN SOUTH-WESTERN FINLAND, Water, air and soil pollution, 85(3), 1995, pp. 1727-1732
Distribution and fluxes of copper within Pinus sylvestris stands were
studied during 1992 - 1994 along a heavy-metal pollution gradient in s
outh-western Finland. The stands are situated at distances of 0.5, 4 a
cid 8 km from a copper-nickel smelter that started operating in 1945 a
t Harjavalta. According to the results, copper concentrations in the s
oil, in the understorey vegetation and in the trees increased steeply
towards the smelter. Almost 50 years' accumulation of heavy metals in
the soil has caused direct toxic effects to soil microbes, thus decrea
sing decomposition and nutrient mineralisation. During the past few ye
ars, sulphur and heavy metal emissions ham the copper and nickel smelt
er have been radically decreased. However, the heavy metals which have
been accumulating in the soil for decades continue to affect the vege
tation for a long time through soil processes. Consequently, long-term
accumulation in the soil has to be taken into account when determinin
g the critical loads of forest ecosystems for heavy metals.