Primary sulfide microinclusions in phenocrysts from Quaternary andesit
e-dacite, dacite, and rhyodacite of the Kamchatka Peninsula and Kurile
Islands consist of pyrrhotite and a copper-bearing phase. The inclusi
ons are sulfide-melt drops trapped in a liquid state or after solidifi
cation by growing phenocrysts. The average chemical composition of the
inclusions (wt %) is as follows: S = 38.42; Fe = 55.28; Cu = 6.03; Ni
= 0.13; and Co = 0.14. Judging by this composition, the acid and inte
rmediate magmas contained 50-230 ppm Cu, which is roughly an order of
magnitude higher than the Cu concentration in solid volcanic rocks.