NITRENE ADDITIONS TO [60]FULLERENE DO NOT GENERATE [6,5]AZIRIDINES

Citation
Ab. Smith et H. Tokuyama, NITRENE ADDITIONS TO [60]FULLERENE DO NOT GENERATE [6,5]AZIRIDINES, Tetrahedron, 52(14), 1996, pp. 5257-5262
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
52
Issue
14
Year of publication
1996
Pages
5257 - 5262
Database
ISI
SICI code
0040-4020(1996)52:14<5257:NAT[DN>2.0.ZU;2-C
Abstract
Addition of nitrenes to C-60 reportedly furnished the first closed [6, 5] fullerene derivatives. However, detailed spectroscopic analysis has revealed that these products are open [6,5] azaannulenes rather than aziridines. (C) 1996 Elsevier Science Ltd