PARTIAL OXIDATION OF ETHANE OVER ALUMINA-BORIA CATALYSTS

Alumina-boria catalysts can be used in selective oxidation of ethane f or ethylene production. The alumina-boria catalysts have been prepared from boric acid using a classical impregnation method on porous and n on-porous alumina. To obtain more dispersed boron oxide on the surface of the support, some alumina-boria samples were prepared by chemical vapour deposition and a comparison with impregnated samples has been p erformed in the ethane selective oxidation. The contribution of gas-ph ase reactions to the formation of ethylene and the role of boron oxide at different percentages on alumina for ethane conversion are discuss ed. A maximum of activity (18.7% conversion) was observed with the sam ple with 30 wt.-% boron oxide on non-porous alumina. The main product was ethylene (16.7% yield) while CO and CH4 were the secondary product s, coming from the decomposition of ethylene. A correlation has been d emonstrated between catalytic activity and the acidity of the alumina- boria catalysts. The boron oxide (with its specific acidity) was respo nsible for the activation of ethane and for the stabilisation of the e thylhydroxyperoxide radical formed during the reaction and favouring t he partial oxidation reaction leading to ethylene formation while alum ina was shown to result into deep oxidation due to its too strong acid ic sites. It is concluded that the role of alumina consists mainly in dispersing boria, resulting in a much more selective catalyst for etha ne oxidation to ethylene than the support itself.