The formation of misfit dislocation was studied in GaAs homoepitaxial
layers on the substrates containing considerable amount of isoelectron
ic indium. The layers were grown with metal-oxide chemical vapour depo
sition and chemical vapour deposition methods including low temperatur
e process with tertiarbutylarsine arsenic source. The critical conditi
ons of misfit dislocation formation were exceeded up to 5x. The sample
s were examined before and after epitaxial process with a number of di
fferent X-ray topographic and diffractometric methods, including high
resolution synchrotron white beam topography. The crystallographic ide
ntification of the defects was supported by the numerical simulation o
f topographic images. It was found that a number of threading dislocat
ions, continuing in the epitaxial layer from those existing in the sub
strate, did not take part in the formation of misfit dislocations desp
ite a suitable slip system. On the other hand, the formation of misfit
dislocations from small imperfections of epitaxial deposit was proved
in many cases. A reasonable good quality of the layers was confirmed
by the resolution of individual defects and only small broadening of r
ocking curves.