M. Springis et al., POINT-DEFECTS RELATED TO 260 K THERMOSTIMULATED LUMINESCENCE IN ALPHA-AL2O3, Radiation effects and defects in solids, 134(1-4), 1995, pp. 481-483
Thermo- and photostimulated processes are studied in reduced hydrogen
containing alpha-Al2O3 excited by UV light. It is found that UV excita
tion in F absorption band at 90 K results in a ionization of the F-cen
ters and capture of released electrons at defects thus producing an an
isotropy absorption band at 4.2 eV and the dominant thermoluminescence
(TL) peak at 260 K. The 260 K TSL peak is accompanied by complete ble
aching of the 4.2 eV absorption band and vice versa-by light stimulati
on in the region of the 4.2 eV band the 260 K TSL peak disappear and r
eleased electrons recombine with F+-centers, Both the effect of the pr
eliminary high-temperature thermal treatment of samples on formation o
f 4.2 eV-centers and the observed dichroism characteristics allows to
conclude that corresponding complex defect contains hydrogen and can i
nvolve vacancy pair.