OXIDATIVE FRAGMENTATIONS OF SELECTED 1-ALKENYL SULFOXIDES - CHEMICAL AND SPECTROSCOPIC EVIDENCE FOR 1-ALKENESULFINYL CHLORIDES

Authors
SCHWAN AL KALIN ML VAJDA KE XIANG TJ BRILLON D
Citation
Al. Schwan et al., OXIDATIVE FRAGMENTATIONS OF SELECTED 1-ALKENYL SULFOXIDES - CHEMICAL AND SPECTROSCOPIC EVIDENCE FOR 1-ALKENESULFINYL CHLORIDES, Tetrahedron letters, 37(14), 1996, pp. 2345-2348
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
14
Year of publication
1996
Pages
2345 - 2348
Database
ISI
SICI code
0040-4039(1996)37:14<2345:OFOS1S>2.0.ZU;2-R
Abstract
A collection of 1-alkenyl sulfoxides possessing diphenylmethyl, p-meth oxybenzyl or 2-(trimethylsilyl)ethyl groups can be converted to 1-alke nesulfinyl chlorides using SO2Cl2. The 1-alkenesulfinyl chlorides were spectroscopically characterized by IR and were chemically captured as their cyclohexyl or 3-phenylpropyl 1-alkenesulfinate esters. Copyrigh t (C) 1996 Elsevier Science Ltd